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| 个人信息 |
| 姓 名： |
刘译员 [编号]:1690 |
性 别： |
女 |
|
| 擅长专业： |
化工 |
出生年月： |
1985/5/1 |
|
| 民 族： |
汉族 |
所在地区： |
内蒙古 乌兰察布盟 |
|
| 文化程度： |
本科 |
所学专业： |
化学工程与工艺 |
|
| 毕业时间： |
39264 |
毕业学校： |
内蒙古工业大学 |
|
| 第一外语： |
英语 |
等级水平： |
六级，雅思5.5 |
|
|
| 口译等级： |
中级 |
工作经历： |
2 年 |
|
|
| 翻译库信息 |
| 可翻译语种： |
英语 |
|
|
| 目前所在地： |
内蒙古 乌兰察布盟 |
| 可提供服务类型： |
笔译 |
| 每周可提供服务时间： |
随机 |
| 证书信息 |
| 证书名称： |
雅思成绩单 |
|
| 获证时间： |
2009/9/1 |
|
| 获得分数： |
5.5 |
|
|
| 证书名称： |
雅思成绩单 |
|
| 获证时间： |
2009/12/1 |
|
| 获得分数： |
5.5 |
|
|
| 工作经历 |
| 工作时期： |
2007/8/1--2009/11/1 |
|
| 公司名称： |
内蒙古奥特普氟化学新材料开发有限公司 |
|
| 公司性质： |
民营企业 |
| 所属行业： |
化工 |
| 所在部门： |
研发中心 |
|
| 职位： |
研究员 |
| 自我评价： |
能够吃苦耐劳，做事认真负责，有较强的团队精神，乐于助人，从不轻言放弃 |
|
|
| 工作时期： |
2007/8/1--2009/11/1 |
|
| 公司名称： |
内蒙古奥特普氟化学新材料开发有限公司 |
|
| 公司性质： |
民营企业 |
| 所属行业： |
化工 |
| 所在部门： |
研发中心 |
|
| 职位： |
研究员 |
| 自我评价： |
吃苦耐劳，做事认真负责，乐于助人，有较强的团队精神。 |
|
|
| 笔译案例信息 |
| 案例标题： |
物料安全资料(MSDS) |
|
| 原文： |
第一部分化学品及企业标识
化学品中文名称：碳化钙；电石
化学品英文名称：calcium carbide；acetylenogen
企业名称：广东光华化学厂有限公司
地址：广东汕头市光华北四路26 号
邮编：515021
电子邮件地址：service@jinhuada.com, sales@jinhuada.com
传真号码：（86）（754）（8115161）
企业应急电话：（86）（754）（8101881）
技术说明书编码：
生效日期： 年月日
第二部分成分/组成信息
纯品■ 混合物□
化学品名称：碳化钙
化学品分子式：CaC2
分子量：64.10
有害物成分含量CAS 号
碳化钙100% 75-20-7
第三部分危险性概述
危险性类别：第4.3 类遇湿易燃物品。
侵入途径：吸入、食入，经皮吸收。
健康危害：损害皮肤，引起皮肤瘙痒、炎症、“鸟眼”样溃疡、黑皮病。皮肤灼伤表现为创面长期不愈及慢
性溃疡型。接触工人出现汗少、牙釉质损害、龋齿发病率增高。
环境危害：无资料。
燃爆危险：本品遇湿易燃。
第四部分急救措施
皮肤接触：立即脱去污染的衣着，用大量流动清水冲洗至少15 分钟。就医。
眼睛接触：立即提起眼睑，用大量流动清水或生理盐水彻底冲洗至少15 分钟。就医。
吸入：脱离现场至空气新鲜处。保持呼吸道通畅。如呼吸困难，给输氧。如呼吸停止，立即进行人工
呼吸。就医。
食入：饮足量温水，催吐。就医。
第五部分消防措施
危险特性：脱离现场至空气新鲜处。保持呼吸道通畅。如呼吸困难，给输氧。如呼吸停止，立即进行人工
呼吸。就医。
有害燃烧产物：炔、一氧化碳、二氧化碳。
灭火方法及灭火剂：禁止用水和泡沫灭火。二氧化碳也无效。须用干燥石墨粉或其它干粉灭火。
灭火注意事项：无资料
物料安全资料(MSDS)
碳化钙
http://www.jinhuada.com Page 2 of 4
第六部分泄露应急处理
个人防护：无资料
环境保护措施：无资料
清洁/吸收措施：无资料
应急处理：隔离泄漏污染区，限制出入。切断火源。建议应急处理人员戴自给正压式呼吸器，穿化学防护
服。不要直接接触泄漏物。小量泄漏：用砂土、干燥石灰或苏打灰混合。使用无火花工具收集于干燥、
洁净、有盖的容器中，转移至安全场所。大量泄漏：用塑料布、帆布覆盖。与有关技术部门联系，确
定清除方法。
第七部分操作处置与储存
操作注意事项：密闭操作，全面排风。操作人员必须经过专门培训，严格遵守操作规程。建议操作人员佩
戴自吸过滤式防尘口罩，戴化学安全防护眼镜，穿化学防护服，戴橡胶手套。避免产生粉尘。避免与酸类、
醇类接触。尤其要注意避免与水接触。搬运时要轻装轻卸，防止包装及容器损坏。配备泄漏应急处理设备。
倒空的容器可能残留有害物。
储存注意事项：储存于阴凉、干燥、通风良好的库房。远离火种、热源。相对湿度保持在75％以下。包装
必须密封，切勿受潮。应与酸类、醇类等分开存放，切忌混储。储区应备有合适的材料收容泄漏物。
第八部分接触控制/个体防护
最高容许浓度：无资料
监测方法：无资料。
工程控制：密闭操作，全面排风。
呼吸系统防护：作业时，应该佩戴自吸过滤式防尘口罩。
眼睛防护：戴化学安全防护眼镜。
身体防护：穿化学防护服。
手防护：戴橡胶手套。
其他防护：工作现场严禁吸烟。注意个人清洁卫生。
第九部分理化特性
外观与性状：无色晶体，工业品为灰黑色块状物，断面为紫色或灰色。PH：无意义
熔点（℃）：2300
沸点（℃）：1107
闪点（℃）：无意义
爆炸上限%（V/V）：无资料
密度：相对密度(水=1) 2.22
相对蒸气密度（空气=1）：无资料
引燃温度（℃）：无资料
爆炸下限%（V/V）：无资料
燃烧热（kJ/mol）：无资料饱和蒸气压（hPa）：无资料
临界温度（℃）：无意义临界压力（MPa）：无意义
辛醇/水分配系数的对数值：无资料
溶解性：无资料。
主要用途：是重要的基本化工原料，主要用于产生乙炔气。也用于有机合成、氧炔焊接等。
第十部分稳定性和反应活性
稳定性：稳定
禁配物：水、醇类、酸类。
物料安全资料(MSDS)
碳化钙
http://www.jinhuada.com Page 3 of 4
避免接触条件：潮湿空气
聚合危害：不能发生
危险分解产物：炔、一氧化碳、二氧化碳。
第十一部分毒理学资料
急性毒性：LD50：无资料
LC50：无资料
亚急性和慢性毒性：无资料
刺激性：无资料
致敏性：无资料
致突变性：无资料
致畸性： 无资料
致癌性：无资料
第十二部分生态学资料
生态毒性：无资料
生物降解性： 无资料
非生物降解性： 无资料
生物富集或生物积累性：无资料
其它有害作用：无资料。
第十三部分废弃处置
废弃物性质：危险弃物
废弃方法：对化学品残存物的处置没有统一的国家法规。化学残存物一般作特殊废物。处置前应参阅国家
和地方有关法规。我们建议您联系相关机构或认可的废物处置公司，他们会建议您如何处置特殊废物。
包装：处置前应参阅国家和地方有关法规。用外理污染物一样的方法来处理污染的包装。如果没有特别规
定，未污染的包装可作家庭废物对待或再循环使用。
第十四部分运输信息
危险货物编号：43025
包装标志：遇湿易燃
UN 编号：1402
包装类别：O52
包装方法：装入坚固的铁桶内，每桶净重为100 公斤，桶口封闭严密，桶内充氮气。桶内未充氮气时，应
装置低压安全阀；螺纹口玻璃瓶、铁盖压口玻璃瓶、塑料瓶或金属桶（罐）外普通木箱。
运输注意事项：运输时铁桶不许倒置。桶内充有氮气时，应在包装上标明，并在货物运单上注明。运输时
运输车辆应配备相应品种和数量的消防器材及泄漏应急处理设备。装运本品的车辆排气管须有阻火装置。
运输过程中要确保容器不泄漏、不倒塌、不坠落、不损坏。严禁与酸类、醇类等混装混运。运输途中应防
曝晒、雨淋，防高温。中途停留时应远离火种、热源。运输用车、船必须干燥，并有良好的防雨设施。车
辆运输完毕应进行彻底清扫。铁路运输时要禁止溜放。
第十五部分法规信息
化学危险物品安全管理条例(1987 年2 月17 日国务院发布)，化学危险物品安全管理条例实施细则(化
劳发[1992] 677 号)，工作场所安全使用化学品规定([1996]劳部发423 号)等法规，针对化学危险品的安全
物料安全资料(MSDS)
碳化钙
http://www.jinhuada.com Page 4 of 4
使用、生产、储存、运输、装卸等方面均作了相应规定；常用危险化学品的分类及标志(GB 13690-92)将
该物质划为第4.3 类遇湿易燃物品。其它法规：电石生产安全技术规定(HGA034-83)。
第十六部分其他信息 |
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| 译文： |
MATERIAL SAFETY DATA SHEET
MSDS No.:
Issue Data:
Section 1-CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Chemical Product Name :Calcium carbide; Acetylenogen
Company Name: Xinglong Fluorichemical Co.,Ltd
Address:Heavy Industry Park,Fengzhen,Inner Mongolia, 012100,China
Email:
Fax:
Emergency Tel:
Section2-COMPOSITION/INFORMATION ON INGREDIENTS
PURY ■ MIXTURE □
Chemical Name: Calcium carbide
Formula: CaC2
Molecular Weight: 64.10
Hazardous Ingredient Content CAS Number
Calcium carbide 100% 75-20-7
Section3-HAZARDOUS IDENTIFICATION
Risk Phrases:The material is classified as 4.3 .Water flammable.
Routs Of Exposure: Inhalation; Ingestion;Skin Contact.
Health Hazards: The material may cause skin damages such as skin itching,inflammation,"bird eyes"canker,black skin disease.It needs a long time to heal the tumefaction area and chronic canker resulted from skin burning.The material may cause less sweat,enamel damage.
Hazards to the Environment: No data.
Fire/Explosion Hazard: Water flammable.
Section4-FIRST AID MEASURES
Skin Contact:Remove contaminated clothes and shoes immediately, rinse skin with plenty of running water at least 15minutes.Consult a physician.
Eye Contact:Separate the eyelids with sterile fingers immediately.Flush eyes with flooding amounts of running water or physiological saline at least 15 minutes.Consult a physician.
Inhalation:Move victim to fresh air.Keep respiratory tract expedite.If breathing is difficult,give oxygen.If breathing stopped,artificial respiration is needed. Consult a physician.
Ingestion:Give plenty of warm water.Emetic.Consult a physician.
Section5-FIRE FIGHTING MEASURES
Hazards Characteristic:Move victim to fresh air.Keep respiratory tract expedite.If breathing is difficult,give oxygen.If breathing stopped,artificial respiration is needed.Consult a physician.
Hazardous Combustion Production:Alkyne,Carbon monoxide,Carbon dioxide.
Extinguishing Methods and Media:Prohibition of water and foam or carbon dioxide. Dry black lead power or other kinds of dry powder may work .
Section6-ACCIDENTAL RELEASE MEASURES
Personal Precautions: No data.
Environmental Precautions: No data.
Methods for Clean up/Absorption: No data.
Emergency Measures:Isolate contaminated areas.No enter confined spaces.Removal of ignition sources.When handling,workers should wear self-contained positive respiratory device and protective clothes.Do not touch the spills and releases directly. For moderate release,mix the releases with silica,dry calcium hydroxide or soda ash.Collect the materials into dry and clean container with cover,then remove it to safe place. For severely releases,cover the releases with plastic fiber and canvas.Contact Technical Agency to determine removal methods.
Section7-HANDLING AND STORAGE
Procedure for Handling:The material should be handled in closed and well-ventilate systems.Use good occupational work practice and observe the operation rules.It is essential that workers in the immediate area wear full face,safety glasses, rubber gloves.Avoid the production of powder.Avoid contact with acid and alcohol,especially avoid contact with water.Handling with care when moving.Avoid physical damage to packages and containers. Accidental release handling devices are needed.Empty containers may still remain some hazardous materials.
Produce for Storage:Store in cool,dry and well-ventilate warehouses.Keep away from ignition source,heat source.Keep Relative Humidity under 75%.Packages should be well sealed.Separate with acid and alcohol.There should be suitable collection containers in the storage areas.
Section8-EXPOSURE CONTROLS/PERSONAL PROTECTION
The Highest Allow Concentration :No data.
Monitoring Methods:No data.
Engineering Controls:Operate in closed and well-ventilate systems.
Respiratory Protection:Workers in the immediate area should wear full face .
Eye Protection:Wear chemical safety glasses.
Hand Protection:Wear rubber gloves.
Other Protection:Cigarettes or tobacco should be prohibited in workplace. Personal cleaning is also very important.
Section9-PHYSICAL AND CHEMICAL PROPERTIES
Appearance:Transparent crystal.Industrial production is gray black cake, and the disconnection area is purple or grey.
PH: No meaningful.
Melting point(℃):2300
Density: Relative density(water=1)2.22
Boiling point(℃):1107
Vapour pressure(air=1):No information
Flash point: No meaningful.
Ignition point(℃):No data
Explosive limit(high):No data
Explosive limit(low):No data
Combustion heat(kg/ mol ):No data
Saturated vapour(hPa)：No data
Critical temperature(℃):No meaningful
Critical pressure(℃):No meaningful
Partition Coefficient（LogKoctanol/water):No data
Use:The production is used as chemical material，mainly used in organic synthesis, autogenous welding and so on。
Section10-CHEMICAL STABILITY AND REACTIVITY INFORMATION
Stability: Stable
Incompatibility: water,alcohol,acid.
Condition to Avoid:Wet air
Hazardous Polymerization: Will not occur
Hazardous Decomposition Production: Alkyne,Carbon monoxide, Carbon dioxide.
Section11-TOXICOLOGICAL INFORMATION
Acute Toxicity Data:LD50:No data
LC50:No data
Subacute and Chronic Toxicity Data: No data
Stimulation:No data
Irritation Data:No data
Mutation Data:No data
Abnormality:No data
Cancer:No data
Section12-ECOLOGICAL INFORMATION
Ecological Toxicity:No data
Biodegradability: No data
Non-biodegradability:No data
Bioenrichment or Bioaccumulation:No data
Other Damage Effects:No data
Section13-DISPOSAL CONSIDERATIONS
Product Disposal Characteristic:Hazardous waste.
Disposal Methods:There is no unified Federal,state and local government regulations for the disposal of chemical remainder.Generally, chemical remainder is disposed as special waste.Refer Federal and local government regulations before disposal.We suggest that you contact with relevant agency or identified waste disposal company,they will tell you how to dispose special waste.
Packaging:Refer Federal and local government regulations before disposal.When disposing contaminants packages,use the same disposal methods as disposing contamiants.If not specified,uncontaminated packages may be treated as household waste or recycled.
Section14-TRANSPORTATION INFORMATION
Hazardous Goods Number:43025
UN Number:1402
Packaging Symbol:Water flammable.
Packaging Class :O52
Packaging Methods:Fill product into firm metal pails which are full of nitrogen.Keep the mouth securely sealed.The net weight of each metal pail may be 100 kilograms.When unfilled nitrogen,there should be low-pressure relief value,screw-mouth glass bottle,iron-cover press-mouth glass bottle, plastic bottle or metal pail(can) wrapped in ordinary wooden trunks .
Procedure for Transportation:No inversion of metal pails in shipping.If the containers are filled with nitrogen,specify on the packages and shipping tickets.There should be corresponding variety and quantity fire fighting equipments and accidental release handling devices during shipping.Vent-pipes of vehicles used may be fixed with fire unit.Make sure no release,callapse,falling,damage occur during shipping. It is essential to separate the product with acid and alcohol during shipping.Avoid overexposure,raining,and overheating.Keep away from ignition source and heat source. Keep vehicles and ships used dry and waterproof device is essential.Clear up the vehicles after shipping.No gliding during railroad transportation.
Section15-REGULATORY INFORMATION
For the hazardous chemical safety use,production,storage,transportation, load and unload,there are corresponding regulations in some acts such as The Safety Management of Hazardous Chemical Regulation(issued by Federal in 2,17,1987),The Safety Management of Hazardous Chemical Administration Detailed Regulation([1992]issued by Chemical Department of Labour NO.677),The Safety Use of Chemical at Workplace Regulation([1996]issued by Chemical Department of Labour NO.43).In The Class and Symbol of Hazardous Chemical, the material is classified as 4.3. Other regulation:The Safety Technic Regulation of Calcium carbide Production(HGA034-83).
Section16-OTHER INFORMATION |
|
|
| 案例标题： |
物料安全资料(MSDS) |
|
| 原文： |
第一部分化学品及企业标识
化学品中文名称：碳化钙；电石
化学品英文名称：calcium carbide；acetylenogen
企业名称：广东光华化学厂有限公司
地址：广东汕头市光华北四路26 号
邮编：515021
电子邮件地址：service@jinhuada.com, sales@jinhuada.com
传真号码：（86）（754）（8115161）
企业应急电话：（86）（754）（8101881）
技术说明书编码：
生效日期： 年月日
第二部分成分/组成信息
纯品■ 混合物□
化学品名称：碳化钙
化学品分子式：CaC2
分子量：64.10
有害物成分含量CAS 号
碳化钙100% 75-20-7
第三部分危险性概述
危险性类别：第4.3 类遇湿易燃物品。
侵入途径：吸入、食入，经皮吸收。
健康危害：损害皮肤，引起皮肤瘙痒、炎症、“鸟眼”样溃疡、黑皮病。皮肤灼伤表现为创面长期不愈及慢
性溃疡型。接触工人出现汗少、牙釉质损害、龋齿发病率增高。
环境危害：无资料。
燃爆危险：本品遇湿易燃。
第四部分急救措施
皮肤接触：立即脱去污染的衣着，用大量流动清水冲洗至少15 分钟。就医。
眼睛接触：立即提起眼睑，用大量流动清水或生理盐水彻底冲洗至少15 分钟。就医。
吸入：脱离现场至空气新鲜处。保持呼吸道通畅。如呼吸困难，给输氧。如呼吸停止，立即进行人工
呼吸。就医。
食入：饮足量温水，催吐。就医。
第五部分消防措施
危险特性：脱离现场至空气新鲜处。保持呼吸道通畅。如呼吸困难，给输氧。如呼吸停止，立即进行人工
呼吸。就医。
有害燃烧产物：炔、一氧化碳、二氧化碳。
灭火方法及灭火剂：禁止用水和泡沫灭火。二氧化碳也无效。须用干燥石墨粉或其它干粉灭火。
灭火注意事项：无资料
物料安全资料(MSDS)
碳化钙
http://www.jinhuada.com Page 2 of 4
第六部分泄露应急处理
个人防护：无资料
环境保护措施：无资料
清洁/吸收措施：无资料
应急处理：隔离泄漏污染区，限制出入。切断火源。建议应急处理人员戴自给正压式呼吸器，穿化学防护
服。不要直接接触泄漏物。小量泄漏：用砂土、干燥石灰或苏打灰混合。使用无火花工具收集于干燥、
洁净、有盖的容器中，转移至安全场所。大量泄漏：用塑料布、帆布覆盖。与有关技术部门联系，确
定清除方法。
第七部分操作处置与储存
操作注意事项：密闭操作，全面排风。操作人员必须经过专门培训，严格遵守操作规程。建议操作人员佩
戴自吸过滤式防尘口罩，戴化学安全防护眼镜，穿化学防护服，戴橡胶手套。避免产生粉尘。避免与酸类、
醇类接触。尤其要注意避免与水接触。搬运时要轻装轻卸，防止包装及容器损坏。配备泄漏应急处理设备。
倒空的容器可能残留有害物。
储存注意事项：储存于阴凉、干燥、通风良好的库房。远离火种、热源。相对湿度保持在75％以下。包装
必须密封，切勿受潮。应与酸类、醇类等分开存放，切忌混储。储区应备有合适的材料收容泄漏物。
第八部分接触控制/个体防护
最高容许浓度：无资料
监测方法：无资料。
工程控制：密闭操作，全面排风。
呼吸系统防护：作业时，应该佩戴自吸过滤式防尘口罩。
眼睛防护：戴化学安全防护眼镜。
身体防护：穿化学防护服。
手防护：戴橡胶手套。
其他防护：工作现场严禁吸烟。注意个人清洁卫生。
第九部分理化特性
外观与性状：无色晶体，工业品为灰黑色块状物，断面为紫色或灰色。PH：无意义
熔点（℃）：2300
沸点（℃）：1107
闪点（℃）：无意义
爆炸上限%（V/V）：无资料
密度：相对密度(水=1) 2.22
相对蒸气密度（空气=1）：无资料
引燃温度（℃）：无资料
爆炸下限%（V/V）：无资料
燃烧热（kJ/mol）：无资料饱和蒸气压（hPa）：无资料
临界温度（℃）：无意义临界压力（MPa）：无意义
辛醇/水分配系数的对数值：无资料
溶解性：无资料。
主要用途：是重要的基本化工原料，主要用于产生乙炔气。也用于有机合成、氧炔焊接等。
第十部分稳定性和反应活性
稳定性：稳定
禁配物：水、醇类、酸类。
物料安全资料(MSDS)
碳化钙
http://www.jinhuada.com Page 3 of 4
避免接触条件：潮湿空气
聚合危害：不能发生
危险分解产物：炔、一氧化碳、二氧化碳。
第十一部分毒理学资料
急性毒性：LD50：无资料
LC50：无资料
亚急性和慢性毒性：无资料
刺激性：无资料
致敏性：无资料
致突变性：无资料
致畸性： 无资料
致癌性：无资料
第十二部分生态学资料
生态毒性：无资料
生物降解性： 无资料
非生物降解性： 无资料
生物富集或生物积累性：无资料
其它有害作用：无资料。
第十三部分废弃处置
废弃物性质：危险弃物
废弃方法：对化学品残存物的处置没有统一的国家法规。化学残存物一般作特殊废物。处置前应参阅国家
和地方有关法规。我们建议您联系相关机构或认可的废物处置公司，他们会建议您如何处置特殊废物。
包装：处置前应参阅国家和地方有关法规。用外理污染物一样的方法来处理污染的包装。如果没有特别规
定，未污染的包装可作家庭废物对待或再循环使用。
第十四部分运输信息
危险货物编号：43025
包装标志：遇湿易燃
UN 编号：1402
包装类别：O52
包装方法：装入坚固的铁桶内，每桶净重为100 公斤，桶口封闭严密，桶内充氮气。桶内未充氮气时，应
装置低压安全阀；螺纹口玻璃瓶、铁盖压口玻璃瓶、塑料瓶或金属桶（罐）外普通木箱。
运输注意事项：运输时铁桶不许倒置。桶内充有氮气时，应在包装上标明，并在货物运单上注明。运输时
运输车辆应配备相应品种和数量的消防器材及泄漏应急处理设备。装运本品的车辆排气管须有阻火装置。
运输过程中要确保容器不泄漏、不倒塌、不坠落、不损坏。严禁与酸类、醇类等混装混运。运输途中应防
曝晒、雨淋，防高温。中途停留时应远离火种、热源。运输用车、船必须干燥，并有良好的防雨设施。车
辆运输完毕应进行彻底清扫。铁路运输时要禁止溜放。
第十五部分法规信息
化学危险物品安全管理条例(1987 年2 月17 日国务院发布)，化学危险物品安全管理条例实施细则(化
劳发[1992] 677 号)，工作场所安全使用化学品规定([1996]劳部发423 号)等法规，针对化学危险品的安全
物料安全资料(MSDS)
碳化钙
http://www.jinhuada.com Page 4 of 4
使用、生产、储存、运输、装卸等方面均作了相应规定；常用危险化学品的分类及标志(GB 13690-92)将
该物质划为第4.3 类遇湿易燃物品。其它法规：电石生产安全技术规定(HGA034-83)。
第十六部分其他信息 |
|
| 译文： |
MATERIAL SAFETY DATA SHEET
MSDS No.:
Issue Data:
Section 1-CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Chemical Product Name :Calcium carbide; Acetylenogen
Company Name: Xinglong Fluorichemical Co.,Ltd
Address:Heavy Industry Park,Fengzhen,Inner Mongolia, 012100,China
Email:
Fax:
Emergency Tel:
Section2-COMPOSITION/INFORMATION ON INGREDIENTS
PURY ■ MIXTURE □
Chemical Name: Calcium carbide
Formula: CaC2
Molecular Weight: 64.10
Hazardous Ingredient Content CAS Number
Calcium carbide 100% 75-20-7
Section3-HAZARDOUS IDENTIFICATION
Risk Phrases:The material is classified as 4.3 .Water flammable.
Routs Of Exposure: Inhalation; Ingestion;Skin Contact.
Health Hazards: The material may cause skin damages such as skin itching,inflammation,"bird eyes"canker,black skin disease.It needs a long time to heal the tumefaction area and chronic canker resulted from skin burning.The material may cause less sweat,enamel damage.
Hazards to the Environment: No data.
Fire/Explosion Hazard: Water flammable.
Section4-FIRST AID MEASURES
Skin Contact:Remove contaminated clothes and shoes immediately, rinse skin with plenty of running water at least 15minutes.Consult a physician.
Eye Contact:Separate the eyelids with sterile fingers immediately.Flush eyes with flooding amounts of running water or physiological saline at least 15 minutes.Consult a physician.
Inhalation:Move victim to fresh air.Keep respiratory tract expedite.If breathing is difficult,give oxygen.If breathing stopped,artificial respiration is needed. Consult a physician.
Ingestion:Give plenty of warm water.Emetic.Consult a physician.
Section5-FIRE FIGHTING MEASURES
Hazards Characteristic:Move victim to fresh air.Keep respiratory tract expedite.If breathing is difficult,give oxygen.If breathing stopped,artificial respiration is needed.Consult a physician.
Hazardous Combustion Production:Alkyne,Carbon monoxide,Carbon dioxide.
Extinguishing Methods and Media:Prohibition of water and foam or carbon dioxide. Dry black lead power or other kinds of dry powder may work .
Section6-ACCIDENTAL RELEASE MEASURES
Personal Precautions: No data.
Environmental Precautions: No data.
Methods for Clean up/Absorption: No data.
Emergency Measures:Isolate contaminated areas.No enter confined spaces.Removal of ignition sources.When handling,workers should wear self-contained positive respiratory device and protective clothes.Do not touch the spills and releases directly. For moderate release,mix the releases with silica,dry calcium hydroxide or soda ash.Collect the materials into dry and clean container with cover,then remove it to safe place. For severely releases,cover the releases with plastic fiber and canvas.Contact Technical Agency to determine removal methods.
Section7-HANDLING AND STORAGE
Procedure for Handling:The material should be handled in closed and well-ventilate systems.Use good occupational work practice and observe the operation rules.It is essential that workers in the immediate area wear full face,safety glasses, rubber gloves.Avoid the production of powder.Avoid contact with acid and alcohol,especially avoid contact with water.Handling with care when moving.Avoid physical damage to packages and containers. Accidental release handling devices are needed.Empty containers may still remain some hazardous materials.
Produce for Storage:Store in cool,dry and well-ventilate warehouses.Keep away from ignition source,heat source.Keep Relative Humidity under 75%.Packages should be well sealed.Separate with acid and alcohol.There should be suitable collection containers in the storage areas.
Section8-EXPOSURE CONTROLS/PERSONAL PROTECTION
The Highest Allow Concentration :No data.
Monitoring Methods:No data.
Engineering Controls:Operate in closed and well-ventilate systems.
Respiratory Protection:Workers in the immediate area should wear full face .
Eye Protection:Wear chemical safety glasses.
Hand Protection:Wear rubber gloves.
Other Protection:Cigarettes or tobacco should be prohibited in workplace. Personal cleaning is also very important.
Section9-PHYSICAL AND CHEMICAL PROPERTIES
Appearance:Transparent crystal.Industrial production is gray black cake, and the disconnection area is purple or grey.
PH: No meaningful.
Melting point(℃):2300
Density: Relative density(water=1)2.22
Boiling point(℃):1107
Vapour pressure(air=1):No information
Flash point: No meaningful.
Ignition point(℃):No data
Explosive limit(high):No data
Explosive limit(low):No data
Combustion heat(kg/ mol ):No data
Saturated vapour(hPa)：No data
Critical temperature(℃):No meaningful
Critical pressure(℃):No meaningful
Partition Coefficient（LogKoctanol/water):No data
Use:The production is used as chemical material，mainly used in organic synthesis, autogenous welding and so on。
Section10-CHEMICAL STABILITY AND REACTIVITY INFORMATION
Stability: Stable
Incompatibility: water,alcohol,acid.
Condition to Avoid:Wet air
Hazardous Polymerization: Will not occur
Hazardous Decomposition Production: Alkyne,Carbon monoxide, Carbon dioxide.
Section11-TOXICOLOGICAL INFORMATION
Acute Toxicity Data:LD50:No data
LC50:No data
Subacute and Chronic Toxicity Data: No data
Stimulation:No data
Irritation Data:No data
Mutation Data:No data
Abnormality:No data
Cancer:No data
Section12-ECOLOGICAL INFORMATION
Ecological Toxicity:No data
Biodegradability: No data
Non-biodegradability:No data
Bioenrichment or Bioaccumulation:No data
Other Damage Effects:No data
Section13-DISPOSAL CONSIDERATIONS
Product Disposal Characteristic:Hazardous waste.
Disposal Methods:There is no unified Federal,state and local government regulations for the disposal of chemical remainder.Generally, chemical remainder is disposed as special waste.Refer Federal and local government regulations before disposal.We suggest that you contact with relevant agency or identified waste disposal company,they will tell you how to dispose special waste.
Packaging:Refer Federal and local government regulations before disposal.When disposing contaminants packages,use the same disposal methods as disposing contamiants.If not specified,uncontaminated packages may be treated as household waste or recycled.
Section14-TRANSPORTATION INFORMATION
Hazardous Goods Number:43025
UN Number:1402
Packaging Symbol:Water flammable.
Packaging Class :O52
Packaging Methods:Fill product into firm metal pails which are full of nitrogen.Keep the mouth securely sealed.The net weight of each metal pail may be 100 kilograms.When unfilled nitrogen,there should be low-pressure relief value,screw-mouth glass bottle,iron-cover press-mouth glass bottle, plastic bottle or metal pail(can) wrapped in ordinary wooden trunks .
Procedure for Transportation:No inversion of metal pails in shipping.If the containers are filled with nitrogen,specify on the packages and shipping tickets.There should be corresponding variety and quantity fire fighting equipments and accidental release handling devices during shipping.Vent-pipes of vehicles used may be fixed with fire unit.Make sure no release,callapse,falling,damage occur during shipping. It is essential to separate the product with acid and alcohol during shipping.Avoid overexposure,raining,and overheating.Keep away from ignition source and heat source. Keep vehicles and ships used dry and waterproof device is essential.Clear up the vehicles after shipping.No gliding during railroad transportation.
Section15-REGULATORY INFORMATION
For the hazardous chemical safety use,production,storage,transportation, load and unload,there are corresponding regulations in some acts such as The Safety Management of Hazardous Chemical Regulation(issued by Federal in 2,17,1987),The Safety Management of Hazardous Chemical Administration Detailed Regulation([1992]issued by Chemical Department of Labour NO.677),The Safety Use of Chemical at Workplace Regulation([1996]issued by Chemical Department of Labour NO.43).In The Class and Symbol of Hazardous Chemical, the material is classified as 4.3. Other regulation:The Safety Technic Regulation of Calcium carbide Production(HGA034-83).
Section16-OTHER INFORMATION |
|
|
| 案例标题： |
物料安全资料(MSDS) |
|
| 原文： |
第一部分化学品及企业标识
化学品中文名称：碳化钙；电石
化学品英文名称：calcium carbide；acetylenogen
企业名称：广东光华化学厂有限公司
地址：广东汕头市光华北四路26 号
邮编：515021
电子邮件地址：service@jinhuada.com, sales@jinhuada.com
传真号码：（86）（754）（8115161）
企业应急电话：（86）（754）（8101881）
技术说明书编码：
生效日期： 年月日
第二部分成分/组成信息
纯品■ 混合物□
化学品名称：碳化钙
化学品分子式：CaC2
分子量：64.10
有害物成分含量CAS 号
碳化钙100% 75-20-7
第三部分危险性概述
危险性类别：第4.3 类遇湿易燃物品。
侵入途径：吸入、食入，经皮吸收。
健康危害：损害皮肤，引起皮肤瘙痒、炎症、“鸟眼”样溃疡、黑皮病。皮肤灼伤表现为创面长期不愈及慢
性溃疡型。接触工人出现汗少、牙釉质损害、龋齿发病率增高。
环境危害：无资料。
燃爆危险：本品遇湿易燃。
第四部分急救措施
皮肤接触：立即脱去污染的衣着，用大量流动清水冲洗至少15 分钟。就医。
眼睛接触：立即提起眼睑，用大量流动清水或生理盐水彻底冲洗至少15 分钟。就医。
吸入：脱离现场至空气新鲜处。保持呼吸道通畅。如呼吸困难，给输氧。如呼吸停止，立即进行人工
呼吸。就医。
食入：饮足量温水，催吐。就医。
第五部分消防措施
危险特性：脱离现场至空气新鲜处。保持呼吸道通畅。如呼吸困难，给输氧。如呼吸停止，立即进行人工
呼吸。就医。
有害燃烧产物：炔、一氧化碳、二氧化碳。
灭火方法及灭火剂：禁止用水和泡沫灭火。二氧化碳也无效。须用干燥石墨粉或其它干粉灭火。
灭火注意事项：无资料
物料安全资料(MSDS)
碳化钙
http://www.jinhuada.com Page 2 of 4
第六部分泄露应急处理
个人防护：无资料
环境保护措施：无资料
清洁/吸收措施：无资料
应急处理：隔离泄漏污染区，限制出入。切断火源。建议应急处理人员戴自给正压式呼吸器，穿化学防护
服。不要直接接触泄漏物。小量泄漏：用砂土、干燥石灰或苏打灰混合。使用无火花工具收集于干燥、
洁净、有盖的容器中，转移至安全场所。大量泄漏：用塑料布、帆布覆盖。与有关技术部门联系，确
定清除方法。
第七部分操作处置与储存
操作注意事项：密闭操作，全面排风。操作人员必须经过专门培训，严格遵守操作规程。建议操作人员佩
戴自吸过滤式防尘口罩，戴化学安全防护眼镜，穿化学防护服，戴橡胶手套。避免产生粉尘。避免与酸类、
醇类接触。尤其要注意避免与水接触。搬运时要轻装轻卸，防止包装及容器损坏。配备泄漏应急处理设备。
倒空的容器可能残留有害物。
储存注意事项：储存于阴凉、干燥、通风良好的库房。远离火种、热源。相对湿度保持在75％以下。包装
必须密封，切勿受潮。应与酸类、醇类等分开存放，切忌混储。储区应备有合适的材料收容泄漏物。
第八部分接触控制/个体防护
最高容许浓度：无资料
监测方法：无资料。
工程控制：密闭操作，全面排风。
呼吸系统防护：作业时，应该佩戴自吸过滤式防尘口罩。
眼睛防护：戴化学安全防护眼镜。
身体防护：穿化学防护服。
手防护：戴橡胶手套。
其他防护：工作现场严禁吸烟。注意个人清洁卫生。
第九部分理化特性
外观与性状：无色晶体，工业品为灰黑色块状物，断面为紫色或灰色。PH：无意义
熔点（℃）：2300
沸点（℃）：1107
闪点（℃）：无意义
爆炸上限%（V/V）：无资料
密度：相对密度(水=1) 2.22
相对蒸气密度（空气=1）：无资料
引燃温度（℃）：无资料
爆炸下限%（V/V）：无资料
燃烧热（kJ/mol）：无资料饱和蒸气压（hPa）：无资料
临界温度（℃）：无意义临界压力（MPa）：无意义
辛醇/水分配系数的对数值：无资料
溶解性：无资料。
主要用途：是重要的基本化工原料，主要用于产生乙炔气。也用于有机合成、氧炔焊接等。
第十部分稳定性和反应活性
稳定性：稳定
禁配物：水、醇类、酸类。
物料安全资料(MSDS)
碳化钙
http://www.jinhuada.com Page 3 of 4
避免接触条件：潮湿空气
聚合危害：不能发生
危险分解产物：炔、一氧化碳、二氧化碳。
第十一部分毒理学资料
急性毒性：LD50：无资料
LC50：无资料
亚急性和慢性毒性：无资料
刺激性：无资料
致敏性：无资料
致突变性：无资料
致畸性： 无资料
致癌性：无资料
第十二部分生态学资料
生态毒性：无资料
生物降解性： 无资料
非生物降解性： 无资料
生物富集或生物积累性：无资料
其它有害作用：无资料。
第十三部分废弃处置
废弃物性质：危险弃物
废弃方法：对化学品残存物的处置没有统一的国家法规。化学残存物一般作特殊废物。处置前应参阅国家
和地方有关法规。我们建议您联系相关机构或认可的废物处置公司，他们会建议您如何处置特殊废物。
包装：处置前应参阅国家和地方有关法规。用外理污染物一样的方法来处理污染的包装。如果没有特别规
定，未污染的包装可作家庭废物对待或再循环使用。
第十四部分运输信息
危险货物编号：43025
包装标志：遇湿易燃
UN 编号：1402
包装类别：O52
包装方法：装入坚固的铁桶内，每桶净重为100 公斤，桶口封闭严密，桶内充氮气。桶内未充氮气时，应
装置低压安全阀；螺纹口玻璃瓶、铁盖压口玻璃瓶、塑料瓶或金属桶（罐）外普通木箱。
运输注意事项：运输时铁桶不许倒置。桶内充有氮气时，应在包装上标明，并在货物运单上注明。运输时
运输车辆应配备相应品种和数量的消防器材及泄漏应急处理设备。装运本品的车辆排气管须有阻火装置。
运输过程中要确保容器不泄漏、不倒塌、不坠落、不损坏。严禁与酸类、醇类等混装混运。运输途中应防
曝晒、雨淋，防高温。中途停留时应远离火种、热源。运输用车、船必须干燥，并有良好的防雨设施。车
辆运输完毕应进行彻底清扫。铁路运输时要禁止溜放。
第十五部分法规信息
化学危险物品安全管理条例(1987 年2 月17 日国务院发布)，化学危险物品安全管理条例实施细则(化
劳发[1992] 677 号)，工作场所安全使用化学品规定([1996]劳部发423 号)等法规，针对化学危险品的安全
物料安全资料(MSDS)
碳化钙
http://www.jinhuada.com Page 4 of 4
使用、生产、储存、运输、装卸等方面均作了相应规定；常用危险化学品的分类及标志(GB 13690-92)将
该物质划为第4.3 类遇湿易燃物品。其它法规：电石生产安全技术规定(HGA034-83)。
第十六部分其他信息 |
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MATERIAL SAFETY DATA SHEET
MSDS No.:
Issue Data:
Section 1-CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Chemical Product Name :Calcium carbide; Acetylenogen
Company Name: Xinglong Fluorichemical Co.,Ltd
Address:Heavy Industry Park,Fengzhen,Inner Mongolia, 012100,China
Email:
Fax:
Emergency Tel:
Section2-COMPOSITION/INFORMATION ON INGREDIENTS
PURY ■ MIXTURE □
Chemical Name: Calcium carbide
Formula: CaC2
Molecular Weight: 64.10
Hazardous Ingredient Content CAS Number
Calcium carbide 100% 75-20-7
Section3-HAZARDOUS IDENTIFICATION
Risk Phrases:The material is classified as 4.3 .Water flammable.
Routs Of Exposure: Inhalation; Ingestion;Skin Contact.
Health Hazards: The material may cause skin damages such as skin itching,inflammation,"bird eyes"canker,black skin disease.It needs a long time to heal the tumefaction area and chronic canker resulted from skin burning.The material may cause less sweat,enamel damage.
Hazards to the Environment: No data.
Fire/Explosion Hazard: Water flammable.
Section4-FIRST AID MEASURES
Skin Contact:Remove contaminated clothes and shoes immediately, rinse skin with plenty of running water at least 15minutes.Consult a physician.
Eye Contact:Separate the eyelids with sterile fingers immediately.Flush eyes with flooding amounts of running water or physiological saline at least 15 minutes.Consult a physician.
Inhalation:Move victim to fresh air.Keep respiratory tract expedite.If breathing is difficult,give oxygen.If breathing stopped,artificial respiration is needed. Consult a physician.
Ingestion:Give plenty of warm water.Emetic.Consult a physician.
Section5-FIRE FIGHTING MEASURES
Hazards Characteristic:Move victim to fresh air.Keep respiratory tract expedite.If breathing is difficult,give oxygen.If breathing stopped,artificial respiration is needed.Consult a physician.
Hazardous Combustion Production:Alkyne,Carbon monoxide,Carbon dioxide.
Extinguishing Methods and Media:Prohibition of water and foam or carbon dioxide. Dry black lead power or other kinds of dry powder may work .
Section6-ACCIDENTAL RELEASE MEASURES
Personal Precautions: No data.
Environmental Precautions: No data.
Methods for Clean up/Absorption: No data.
Emergency Measures:Isolate contaminated areas.No enter confined spaces.Removal of ignition sources.When handling,workers should wear self-contained positive respiratory device and protective clothes.Do not touch the spills and releases directly. For moderate release,mix the releases with silica,dry calcium hydroxide or soda ash.Collect the materials into dry and clean container with cover,then remove it to safe place. For severely releases,cover the releases with plastic fiber and canvas.Contact Technical Agency to determine removal methods.
Section7-HANDLING AND STORAGE
Procedure for Handling:The material should be handled in closed and well-ventilate systems.Use good occupational work practice and observe the operation rules.It is essential that workers in the immediate area wear full face,safety glasses, rubber gloves.Avoid the production of powder.Avoid contact with acid and alcohol,especially avoid contact with water.Handling with care when moving.Avoid physical damage to packages and containers. Accidental release handling devices are needed.Empty containers may still remain some hazardous materials.
Produce for Storage:Store in cool,dry and well-ventilate warehouses.Keep away from ignition source,heat source.Keep Relative Humidity under 75%.Packages should be well sealed.Separate with acid and alcohol.There should be suitable collection containers in the storage areas.
Section8-EXPOSURE CONTROLS/PERSONAL PROTECTION
The Highest Allow Concentration :No data.
Monitoring Methods:No data.
Engineering Controls:Operate in closed and well-ventilate systems.
Respiratory Protection:Workers in the immediate area should wear full face .
Eye Protection:Wear chemical safety glasses.
Hand Protection:Wear rubber gloves.
Other Protection:Cigarettes or tobacco should be prohibited in workplace. Personal cleaning is also very important.
Section9-PHYSICAL AND CHEMICAL PROPERTIES
Appearance:Transparent crystal.Industrial production is gray black cake, and the disconnection area is purple or grey.
PH: No meaningful.
Melting point(℃):2300
Density: Relative density(water=1)2.22
Boiling point(℃):1107
Vapour pressure(air=1):No information
Flash point: No meaningful.
Ignition point(℃):No data
Explosive limit(high):No data
Explosive limit(low):No data
Combustion heat(kg/ mol ):No data
Saturated vapour(hPa)：No data
Critical temperature(℃):No meaningful
Critical pressure(℃):No meaningful
Partition Coefficient（LogKoctanol/water):No data
Use:The production is used as chemical material，mainly used in organic synthesis, autogenous welding and so on。
Section10-CHEMICAL STABILITY AND REACTIVITY INFORMATION
Stability: Stable
Incompatibility: water,alcohol,acid.
Condition to Avoid:Wet air
Hazardous Polymerization: Will not occur
Hazardous Decomposition Production: Alkyne,Carbon monoxide, Carbon dioxide.
Section11-TOXICOLOGICAL INFORMATION
Acute Toxicity Data:LD50:No data
LC50:No data
Subacute and Chronic Toxicity Data: No data
Stimulation:No data
Irritation Data:No data
Mutation Data:No data
Abnormality:No data
Cancer:No data
Section12-ECOLOGICAL INFORMATION
Ecological Toxicity:No data
Biodegradability: No data
Non-biodegradability:No data
Bioenrichment or Bioaccumulation:No data
Other Damage Effects:No data
Section13-DISPOSAL CONSIDERATIONS
Product Disposal Characteristic:Hazardous waste.
Disposal Methods:There is no unified Federal,state and local government regulations for the disposal of chemical remainder.Generally, chemical remainder is disposed as special waste.Refer Federal and local government regulations before disposal.We suggest that you contact with relevant agency or identified waste disposal company,they will tell you how to dispose special waste.
Packaging:Refer Federal and local government regulations before disposal.When disposing contaminants packages,use the same disposal methods as disposing contamiants.If not specified,uncontaminated packages may be treated as household waste or recycled.
Section14-TRANSPORTATION INFORMATION
Hazardous Goods Number:43025
UN Number:1402
Packaging Symbol:Water flammable.
Packaging Class :O52
Packaging Methods:Fill product into firm metal pails which are full of nitrogen.Keep the mouth securely sealed.The net weight of each metal pail may be 100 kilograms.When unfilled nitrogen,there should be low-pressure relief value,screw-mouth glass bottle,iron-cover press-mouth glass bottle, plastic bottle or metal pail(can) wrapped in ordinary wooden trunks .
Procedure for Transportation:No inversion of metal pails in shipping.If the containers are filled with nitrogen,specify on the packages and shipping tickets.There should be corresponding variety and quantity fire fighting equipments and accidental release handling devices during shipping.Vent-pipes of vehicles used may be fixed with fire unit.Make sure no release,callapse,falling,damage occur during shipping. It is essential to separate the product with acid and alcohol during shipping.Avoid overexposure,raining,and overheating.Keep away from ignition source and heat source. Keep vehicles and ships used dry and waterproof device is essential.Clear up the vehicles after shipping.No gliding during railroad transportation.
Section15-REGULATORY INFORMATION
For the hazardous chemical safety use,production,storage,transportation, load and unload,there are corresponding regulations in some acts such as The Safety Management of Hazardous Chemical Regulation(issued by Federal in 2,17,1987),The Safety Management of Hazardous Chemical Administration Detailed Regulation([1992]issued by Chemical Department of Labour NO.677),The Safety Use of Chemical at Workplace Regulation([1996]issued by Chemical Department of Labour NO.43).In The Class and Symbol of Hazardous Chemical, the material is classified as 4.3. Other regulation:The Safety Technic Regulation of Calcium carbide Production(HGA034-83).
Section16-OTHER INFORMATION |
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